Properties of Polymers: Edition 3
D.W. van Krevelen
Des 2012 · Elsevier
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Properties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions summarizes the latest developments regarding polymers, their properties in relation to chemical structure, and methods for estimating and predicting numerical properties from chemical structure. In particular, it examines polymer electrical properties, magnetic properties, and mechanical properties, as well as their crystallization and environmental behavior and failure. The rheological properties of polymer melts and polymer solutions are also considered. Organized into seven parts encompassing 27 chapters, this book begins with an overview of polymer science and engineering, including the typology of polymers and their properties. It then turns to a discussion of thermophysical properties, from transition temperatures to volumetric and calorimetric properties, along with the cohesive aspects and conformation statistics. It also introduces the reader to the behavior of polymers in electromagnetic and mechanical fields of force. The book covers the quantities that influence the transport of heat, momentum, and matter, particularly heat conductivity, viscosity, and diffusivity; properties that control the chemical stability and breakdown of polymers; and polymer properties as an integral concept, with emphasis on processing and product properties. Readers will find tables that give valuable (numerical) data on polymers and include a survey of the group contributions (increments) of almost every additive function considered. This book is a valuable resource for anyone working on practical problems in the field of polymers, including organic chemists, chemical engineers, polymer processers, polymer technologists, and both graduate and PhD students.
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Dirk Willem van Krevelen (8 November 1914, Rotterdam – 27 October 2001, Arnhem) was a prominent Dutch chemical engineer, coal and polymer scientist. He successfully combined an industrial career, managing a research division at DSM, and an academic one, as a professor of Delft Technical College. His contributions spanned a wide range of research fields, and his name is linked to the van Krevelen–Hoftyzer diagram for chemical gas absorption, the Mars–van Krevelen mechanism for catalytic oxidation reactions, the van Krevelen–Chermin method to estimate the free energy of organic compounds, the van Krevelen diagram that is used in coal and coal processes, the van Krevelen method to calculate additive properties of polymers, and the van Krevelen–Hoftyzer relationship on the viscosity of polymer fluids. He authored numerous scientific publications and several classic monographs, amongst which are Coal: Typology, Chemistry, Physics, Constitution and Properties of Polymers: Correlations with Chemical Structure. His name is retained in the author listing for the planned fifth edition for this book out of tribute to his vast contribution with the blessing of his son Laurens van Krevelen.
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